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Effect Of Roll Pressure On The Compression And Electrical Conductivity Of Electrodes
1. Preface
This paper adopts the Battery Electrode Resistivity Tester(BER2500) to test the electrical conductivity of graphite electrodes under different compaction densities, i.e., different roll pressures. At the same time, the test and analysis of the compression performance of the electrode is carried out by combining with the flat pressing structure of the equipment, which provides a new method for the evaluation of lithium-ion battery electrode roll pressing production process.
In 2022, Zhang et al ¹ combined discrete element method numerical simulation and calendering test to carry out a systematic microscopic and macroscopic study of the electrode roll compression process, and supplemented the electrode compression prediction model using the Heckel equation, and Figure 1 shows a schematic diagram of the stress and displacement curves of the electrode sheet in the compression process. In the paper, it is clarified that the electrode deformation is related to particle pulverization, secondary particle fusion, binder network compression and collector surface deformation. Meanwhile, the results show that the increase in electrical conductivity is related to the improved conductive paths inside the electrode on one hand, and the tightening of the contact between the coating and the collector on the other hand.
Figure 1. Schematic diagram of the force-displacement curve of the electrode sheet
(Green areas represent experimental results, gray areas represent simulation results)
1. Experimental Equipment and Test Methods
1.1 Experimental Equipmentd
The test equipment model is BER2500 (IEST), the electrode diameter is 14mm, and the applied pressure range is 5~60MPa. The device is shown in Figures 2(a) and 2(b).
Figure 2. (a) BER2500 Appearance; (b) BER2500 structure diagram
1.2 Sample Preparation and Test
1.2.1 After uniformly coating the slurry under the same process formula conditions, we use different pressures such as small, medium and large to carry out roll pressing to obtain four kinds of compacted finished electrode sheets in 1/2/3/4 , wherein the pressure of the electrode sheet rolling is 1<2<3<4. The compaction density of the four electrode sheets is calculated respectively by cutting-thickness-weighing method, and the compaction density also shows 1(1.35g/cm³)<2(1.5g/cm³)<3(1.6g/cm³)<3(1.6g/cm³) cm³)<4 (1.65g/cm³), that is, as the rolling pressure increases, the compaction density also shows an increasing trend.
1.2.2 Combining with BER2500 equipment, using the steady-state test mode, with 5-60MPa, 5MPa interval, and holding pressure for 15s, the compression and resistance of electrode sheets with different compaction densities are compared and tested. The specific process of the test is: apply a certain pressure from 5MPa and keep it for 15s, the electrode sheet is compressed, and record the thickness and resistance of the electrode sheet at the same time; then increase the pressure at intervals of 5MPa, and then record the thickness and resistance of the electrode sheet, and so on until 60MPa; then gradually reduce the applied pressure to unload and record the thickness and resistance.
2. Data Analysis
After obtaining four electrodes with different compaction densities, use the steady-state mode to carry out loading compression-unloading rebound tests on the electrode sheet under different quantitative pressure conditions, record the thickness change, and use the initial pressure point of 5MPa as a benchmark to calculate the thickness deformation Perform normalized calculations to obtain the stress-strain curves of different electrode sheets (as shown in Figure 3), and summarize their deformations (as shown in Table 1). It can be seen from the result chart that with the increase of the electrode sheet rolling pressure, the maximum deformation, reversible deformation and irreversible deformation of the four electrode sheets gradually decrease (1>2>3>4), but the decreasing trend Gradually slow down. This change trend is closely related to the filling and compaction effect of the powder in the electrode sheet coating, including the flow and rearrangement of powder particles, elastic and plastic deformation, and crushing. Usually, the electrode sheet calendering process needs to overcome friction, surface force, elastic deformation, plastic deformation and crushing to do work on the electrode coating to compact the electrode.
The material formulation of the coating part designed in this experiment is consistent. Different rolling pressure will directly affect the flow and rearrangement of particles. The increase of rolling pressure can overcome the friction between particles and make the particles arrange more tightly and combine with each other. more closely. Moreover, as the rolling pressure increases, the powder first rearranges and fills the original hole; after the particles are in close contact, the pressure continues to increase, and the particles interact and elastically deform. When the pressure increases to the particle After a certain yield stress, the active particles undergo plastic deformation, which is also the key reason for the gradual increase in compaction density with the increase of rolling pressure. Lithium-ion battery electrode sheet formulations usually also need to add functional additives to the active powder, such as flow aids, binders, conductive agents, etc., which will also affect the change of the overall state of the electrode sheet under different pressures. In the actual electrode sheet production, the electrode sheet is affected by comprehensive factors such as process conditions, roller pressure, tension, speed and powder compression performance. The overall pressure set in the experiment in this paper is relatively small, but the compression performance trend is consistent with the actual production process, which can be used as an effective means of process evaluation.
Figure 3. Stress-strain (compression performance) curves of four kinds of electrode sheets
Table 1. Summary of Four Kinds of Electrode deformation
During the rolling process of lithium-ion battery electrode sheet, the deformation of the width and length of the electrode sheet is very small, and the electrode sheet rolling can reduce the thickness of the coating, increase the compaction density, and improve the adhesion of the coating, so as to stabilize the electrode structure and improve purpose of battery capacity. The rolling process of the electrode sheet is a process in which the mass per unit area is almost constant and the volume is reduced. Between the particles, between the particles and the current collector, they are combined by a binder. The compression in the thickness direction of the electrode sheet is the result of the simultaneous compression of the current collector and the coating, but the change in the thickness of the current collector is relatively small. There is also interaction between the powder particles and the current collector. During the rolling process, the particles will form pits on the current collector, thereby increasing the contact area and cohesion between the coating and the current collector.
Figures 4 and 5 respectively show the thickness variation curves and resistivity variation curves of electrode sheets with four different compaction densities under a series of pressure-applied flat pressures in the steady-state mode. As the pressure increases, the overall thickness of the electrode sheet becomes smaller as a whole. After a certain pressure, the thickness of the electrode sheet tends to be stable. At the same time, the electrode sheet is more likely to rebound when the pressure is low. Therefore, in the variable pressure test, the thickness varies greatly with the pressure. In the resistivity curve, the change trend of electrode sheets 1 and 2 is greater than that of electrode sheets 3 and 4. This is mainly because compared with electrode sheets 1 and 2, the contact between the coating particles of electrode sheets 3 and 4 under large rolling pressure and the the contact between the coating and the current collector is tighter, and the change in the overall thickness of the electrode sheet during the flat compaction measurement is smaller. Compared with the resistivity test results under different pressures, the absolute value of the small rolling pressure electrode sheet is smaller than the large rolling pressure, which may be because the change in the thickness direction of the flattened electrode sheet is easier to make the longitudinal electrical conductivity of the electrode sheet better. In the actual evaluation of electrical conductivity, the most reasonable parameters can be selected for testing in combination with specific needs.
Figure 4. Thickness variation curves of four electrode sheets
Figure 5. Electrical conductivity test curves of four electrode sheets
3. Summary
This article uses the BER2500 series electrode resistance tester equipment to test the compression performance and electrical conductivity of graphite electrodes under different rolling pressures. It can effectively distinguish the performance differences of electrodes under different rolling pressures. The selection of rolling pressure in the actual production process should be reasonably selected in combination with the specific process formula. While increasing the battery capacity, it can also effectively improve the overall electrical conductivity performance of the battery.
4. References
[1] Zhang J, Huang H, Sun J. Investigation on mechanical and microstructural evolution of lithium-ion battery electrode during the calendering process[J]. Powder Technology, 2022, 409: 117828.
[2] BG Westphal et al. Influence of high intensive dry mixing and calendering on relative electrode resistivity determined via an advanced two point approach. Journal of Energy Storage 2017, 11, 76–85
[3] Yang Shaobin, Liang Zheng. Principles and applications of lithium-ion battery manufacturing process[M]. Chemical Industry Press, 2020.
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